Collision rate constants for polarizable ions
نویسندگان
چکیده
منابع مشابه
SHORT COMMUNICATION Collision Rate Constants for Polarizable Ions
Langevin described a model for the interaction between an ion and a neutral nearly a century ago and since then, many modifications have been introduced to adjust for specific circumstances. This work discusses the induced dipole–induced dipole interaction between an ion and a neutral without a permanent dipole and introduces an anisotropic adjustment. A point polarizable ion model (PPI) and an...
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a classical theory is developed which calculates the momentum transfer rate constant between an ion and a non-polar molecule. the model takes into consideration the effect of diffraction outside the capture limit on the rate constants. the theory is used to calculate momentum transfer rate constant for cl- with trans-dichloroethylene and para-difluorobenzene. theoretical results are compared to...
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ژورنال
عنوان ژورنال: Journal of the American Society for Mass Spectrometry
سال: 2003
ISSN: 1044-0305,1879-1123
DOI: 10.1016/s1044-0305(03)00134-x